117067-46-6

Basic information

• Product Name: N-(1-Benzotriazol-1-yl-2-methyl-propyl)-benzamide
• Synonyms: N-(1-Benzotriazol-1-yl-2-methyl-propyl)-benzamide
• CAS NO: 117067-46-6
• Molecular Weight: 294.356
• Mol File: 117067-46-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(1-Benzotriazol-1-yl-2-methyl-propyl)-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-Benzotriazol-1-yl-2-methyl-propyl)-benzamide(117067-46-6)
• EPA Substance Registry System: N-(1-Benzotriazol-1-yl-2-methyl-propyl)-benzamide(117067-46-6)

Safety Data

• Hazardous Substances Data: 117067-46-6(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 55-21-0 benzamide 
• 78-84-2 isobutyraldehyde 
• 117067-47-7 N-(1-Benzotriazol-1-yl-butyl)-benzamide 
• 119020-86-9 N-(1-Benzotriazol-1-yl-hexyl)-benzamide 
• 119020-88-1 N-(1-benzotriazol-1-yl-1-phenylmethyl)acetamide 

Downstream Products

• 139059-32-8 N-(2-Methyl-1-m-tolylsulfanyl-propyl)-benzamide 
• 119020-88-1 N-(1-benzotriazol-1-yl-1-phenylmethyl)acetamide 
• 119020-86-9 N-(1-Benzotriazol-1-yl-hexyl)-benzamide 
• 117067-49-9 N-[1-benzotriazol-1-yl-1-(4-methylphenyl)methyl]acetamide 
• 117067-47-7 N-(1-Benzotriazol-1-yl-butyl)-benzamide 
• 1082512-36-4 4-benzoylamino-5-methyl-1-hexene 
• 5705-57-7 N-isobutyl-benzamide 
• 117067-56-8 N-(1-Isopropyl-3-phenyl-prop-2-ynyl)-benzamide 
• 82894-56-2 3-Benzamino-2-methyl-4-phenyl-butan 
• 42882-36-0 benzyl(2-methylpropyl)amine 
• 95-14-7 1,2,3-Benzotriazole 

Relevant articles and documents

Synthesis of N-[1-(trialkylstannyl)alkyl]amides and -amines by the displacement of benzotriazoles with trialkylstannyllithiums

Condensation of benzotriazole, an aldehyde, and either an amine or amide using the method of Katritzky gave N-[1-benzotriazol-1-yl)alkyl]amides and -amines, which were treated with tributylstannyllithium or trimethylstannyllithium to afford N-[1-(trialkylstannyl)alkyl]amides and -amines, respectively. These compounds are important precursors of nitrogen-substituted organolithium reagents.

THE CHEMISTRY OF BENZOTRIAZOLE. PART 8. A NOVEL TWO-STEP PROCEDURE FOR THE N-ALKYLATION OF AMIDES

Benzotriazole, aldehydes RCHO, and amides R1CONH2 react together with elimination of water to form 1:1:1 adducts which are reduced smoothly by NaBH4 to give the N-substituted amides R1CONHCH2R.Both steps occur in high yields and can be carried out on a large scale, thus comprising a convenient general method for the N-alkylation of amides.