117508-93-7Relevant articles and documents
VICARIOUS NUCLEOPHILIC SUBSTITUTION OF HYDROGEN ORTHO TO THE NITRO GROUP BY TERTIARY CARBANIONS OF α-CHLOROALKYL PHENYL SULPHONES
Mudryk, Boguslav,Makosza, Mieczyslaw
, p. 209 - 214 (2007/10/02)
The tertiary carbanions of α-chloroalkyl phenyl sulphones readily enter the vicarious nucleophilic substitution of hydrogen ortho to the nitro group with a number of 4- and 3-substituted nitrobenzenes, when potassium tert-butoxide/DMF base-solvent system at -40 deg C + -30 deg C is employed.