117784-15-3Relevant articles and documents
On the Synthesis of 3(5)-Carbomethoxy-4-hetarylpyrazoles
Cativiela, Carlos,Villegas, Maria D. Diaz de,Mayoral, Jose A.,Avenoza, Alberto,Roy, Miguel A.
, p. 851 - 855 (2007/10/02)
3(5)-Carbomethoxy-4-hetarylpyrazoles 3 can be obtained by the aromatization of the corresponding cis-3-benzamido-3-carbomethoxy-4-hetaryl-Δ1-pyrazolines 2 obtained by 1,3-dipolar cycloaddition of diazomethane with methyl Z-2-benzamido-3-hetarylpropenoates 1.An explanation, based on FMO theory, for the different reactivity of the dipolarophiles with diazomethane is given.