117972-14-2

Basic information

• Product Name: 4-Pentenoic acid, 2-(phenylsulfonyl)-, methyl ester
• CAS NO: 117972-14-2
• Molecular Formula: C12H14O4S
• Molecular Weight: 254.307
• Mol File: 117972-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, 2-(phenylsulfonyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, 2-(phenylsulfonyl)-, methyl ester(117972-14-2)
• EPA Substance Registry System: 4-Pentenoic acid, 2-(phenylsulfonyl)-, methyl ester(117972-14-2)

Safety Data

• Hazardous Substances Data: 117972-14-2(Hazardous Substances Data)

Upstream product

• 1693-71-6 tris(allyl)borate 
• 34097-60-4 methyl benzenesulfonylacetate 

Relevant articles and documents

Palladium-catalyzed allylic alkylation of carbonucleophiles with allylic borates or allylic alcohols and boron oxide under neutral conditions

Under neutral conditions, Pd(PPh3)4 catalyzes the allylic alkylation of carbonucleophiles with allylic borates in high yields.Moreover, allylic borates are formed in situ from allylic alcohols with boron oxide, and the Pd-catalyzed allylic alkylation was achieved simply by the reaction of allylic alcohols with a nucleophile in the presesnce of boron oxide by a one-pot procedure.The mechanisms of these reactions are discussed.