1182190-65-3Relevant articles and documents
Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C-H functionalization
Choudhury, Joyanta,Dutta, Tapas Kumar,Mandal, Tanmoy,Mohanty, Sunit
supporting information, p. 10182 - 10185 (2021/10/12)
Three-dimensionally propagated imidazolium-containing mesoporous coordination polymer and organic polymer-based platforms were successfully exploited to develop single-site heterogenized Pd-NHC catalysts for oxidative arene/heteroarene C-H functionalization reactions. The catalysts were efficient in directed arene halogenation, and nondirected arene and heteroarene arylation reactions. High catalytic activity, excellent heterogeneity and recyclability were offered by these systems making them promising candidates in the area of heterogeneous C-H functionalization, where efficient catalysts are still scarce.
Palladium-catalyzed monoselective halogenation of C-H bonds: Efficient access to halogenated arylpyrimidines using calcium halides
Song, Bingrui,Zheng, Xiaojian,Mo, Jun,Xu, Bin
supporting information; experimental part, p. 329 - 335 (2010/04/28)
A wide variety of ortho-halogenated arylpyrimidines were prepared with high monoselectivity and functional-group tolerance by using calcium halides as crucial halogenating agents and cupric trifluoroacetate as oxidant in the presence of air.
Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation
Kakiuchi, Fumitoshi,Kochi, Takuya,Mutsutani, Hitoshi,Kobayashi, Noboru,Urano, Seiya,Sato, Mitsuo,Nishiyama, Shigeru,Tanabe, Takamasa
supporting information; experimental part, p. 11310 - 11311 (2011/02/26)
(Chemical Equation Presented) A new strategy for catalytic functionalization of C-H bonds by means of electrochemical oxidation is described. Combination of palladium-catalyzed aromatic C-H bond cleavage and halogenation with electrochemically generated h
