1187224-50-5

Basic information

• Product Name: (4'-phenyl-3,2':6',3''-terpyridine)tetra(acetylacetonato)dizinc(II) monohydrate
• CAS NO: 1187224-50-5
• Molecular Weight: 854.603
• Mol File: 1187224-50-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4'-phenyl-3,2':6',3''-terpyridine)tetra(acetylacetonato)dizinc(II) monohydrate(CAS DataBase Reference)
• NIST Chemistry Reference: (4'-phenyl-3,2':6',3''-terpyridine)tetra(acetylacetonato)dizinc(II) monohydrate(1187224-50-5)
• EPA Substance Registry System: (4'-phenyl-3,2':6',3''-terpyridine)tetra(acetylacetonato)dizinc(II) monohydrate(1187224-50-5)

Safety Data

• Hazardous Substances Data: 1187224-50-5(Hazardous Substances Data)

Upstream product

• 14024-63-6 zinc(II) acetylacetonate 
• 5333-11-9 NSC₅₉₈ 
• 7732-18-5 water 

Relevant articles and documents

The novel ligand 4′-phenyl-3,2′:6′,3′′-terpyridine (L) and the supramolecular structure of the dinuclear complex [Zn2(μ-L)(acac)4] · H2O (acac = acetylacetonato)

The new terpyridyl ligand 4′-phenyl-3,2′:6′,3′′-terpyridine (L) reacts with Zn(acac)2 to produce the dizinc complex [Zn2(μ-L)(acac)4] · H2O (1) (acac = acetylacetonato). The analysis of the crystal structure of this zero-dimensional (0D) complex shows the existence of two Zn(acac)2 centers bridged symmetrically by one μ-L ligand. The key role played by the acac and L ligands and the guest water molecule allows the generation of a series of intermolecular hydrogen bonds of the O-H/O, C-H/O and C-H/π type which give raise to a 3D supramolecular array. The observed C-H/π interactions are so widespread that all the π-rings present in the structure, viz., those belonging to the L ligand as well as the acetylacetonato chelate rings, participate as hydrogen bond acceptors.