119541-41-2

Basic information

• Product Name: 3-Phenyl-N-pyridin-3-yl-thiopropionimidic acid pyridin-2-yl ester
• Synonyms: 3-Phenyl-N-pyridin-3-yl-thiopropionimidic acid pyridin-2-yl ester
• CAS NO: 119541-41-2
• Molecular Weight: 319.43
• Mol File: 119541-41-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Phenyl-N-pyridin-3-yl-thiopropionimidic acid pyridin-2-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenyl-N-pyridin-3-yl-thiopropionimidic acid pyridin-2-yl ester(119541-41-2)
• EPA Substance Registry System: 3-Phenyl-N-pyridin-3-yl-thiopropionimidic acid pyridin-2-yl ester(119541-41-2)

Safety Data

• Hazardous Substances Data: 119541-41-2(Hazardous Substances Data)

Upstream product

• 114050-31-6 3-Phenyl-propionic acid 2-thioxo-2H-pyridin-1-yl ester 
• 85526-38-1 3-pyridyl isocyanide 

Downstream Products

• 77078-54-7 3-phenylthiopropionic acid 
• 114050-31-6 3-Phenyl-propionic acid 2-thioxo-2H-pyridin-1-yl ester 
• 119520-61-5 3-phenylpropanoic dithioperoxyanhydride 
• 645-45-4 hydrocinnamic acid chloride 
• 501-52-0 3-Phenylpropionic acid 
• 119520-49-9 3-phenyl-N-(pyridin-3-yl)propanamide 

Relevant articles and documents

THE INVENTION OF RADICAL REACTIONS PART XVIII. A CONVENIENT SOLUTION TO THE 1-CARBON PROBLEM (R-CO2H --> R-13CO2H)

Radicals generated by photolysis (W light) of esters derived from N-hydroxy-2-thiopyridone react with electrophilic isocyanides 2a and (in the presence of trifluoroacetic acid) 2b to give adducts of type 3.Convenient reaction procedures have been worked out to hydrolyse the adducts to amides of type 5, from which the original acid can be regenerated under mild conditions.The three important acids oleic, linoleic and arachidonic have all given smooth reactions.In suitable examples, quantitative evolution of carbon dioxide and incorporation of 13C without dilution have been demonstrated.This reaction sequence will be useful for the labelling in the carboxyl group of prostaglandins, leukotrienes, and the side chain carboxyls of peptides.