1202357-35-4

Basic information

• Product Name: (4R,5S)-5-phenylthio-4-octanol
• Synonyms: (4R,5S)-5-phenylthio-4-octanol
• CAS NO: 1202357-35-4
• Molecular Weight: 238.394
• Mol File: 1202357-35-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,5S)-5-phenylthio-4-octanol(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5S)-5-phenylthio-4-octanol(1202357-35-4)
• EPA Substance Registry System: (4R,5S)-5-phenylthio-4-octanol(1202357-35-4)

Safety Data

• Hazardous Substances Data: 1202357-35-4(Hazardous Substances Data)

Upstream product

• 191731-56-3 (4S,5S)-4,5-Epoxyoctane 
• 108-98-5 thiophenol 

Downstream Products

• 1202357-36-5 ((4S,5R)-5-chlorooctan-4-yl)(phenyl)sulfane 

Relevant articles and documents

Synthesis and reactivity of enantiomerically enriched thiiranium ions

Enantiomerically enriched thiiranium ion 5 has been prepared by silverassisted ionization of chloro sulfide 4 at -20°C. This thiiranium ion is configurationally stable in solution up to room temperature as demonstrated by the stereospecific capture of the ion by various oxygen- and nitrogen-based nucleophiles. Both isolated olefins and weak Lewis bases can promote the racemization of 5 but these processes can also be suppressed at low temperature. Capture of 5 by methanol is faster than the racemization processes.