120408-88-0Relevant articles and documents
One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine
Kang, Philjun,Lee, Kyu Myung,Lee, Won Koo,Lee, Kyu Hyung,Lee, Byeongno,Cho, Jaeheung,Hur, Nam Hwi
, p. 46203 - 46207 (2015/02/19)
Many amines are liquid and their handling is inconvenient compared with the corresponding solids. We transformed a liquid (S)-(-)-1-phenylethylamine 1 to the corresponding neutral solid form 2 by reacting with carbon dioxide. We performed reductive aminat
New potentially dhelating chiral magnesium amide bases for use in enantioselective deprotonation reactions
Kerr, William J.,Middleditch, Michael,Watson, Allan J. B.
supporting information; experimental part, p. 177 - 180 (2011/03/22)
A series of chiral secondary amines, incorporating a five- or six-membered heterocycle, were synthesised and used to prepare novel chiral magnesium bisamide reagents. These amide bases were subsequently applied within asymmetric deprotonation reactions to