121114-76-9

Basic information

• Product Name: (1-methoxy-1-methylethoxy)benzene
• Synonyms: (1-methoxy-1-methylethoxy)benzene
• CAS NO: 121114-76-9
• Molecular Weight: 166.22
• Mol File: 121114-76-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1-methoxy-1-methylethoxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-methoxy-1-methylethoxy)benzene(121114-76-9)
• EPA Substance Registry System: (1-methoxy-1-methylethoxy)benzene(121114-76-9)

Safety Data

• Hazardous Substances Data: 121114-76-9(Hazardous Substances Data)

Upstream product

• 116-11-0 2-Methoxypropene 
• 108-95-2 phenol 

Relevant articles and documents

Photocatalytic Reductive Formation of α-Tertiary Ethers from Ketals

A general photocatalytic reductive strategy for the construction of unsymmetrical α-tertiary dialkyl ethers is reported. By merging Lewis acid-mediated ketal activation and visible-light photocatalytic reduction, in situ-generated α-alkoxy radicals were found to engage in addition reactions with a variety of olefinic partners. Good reaction efficiency is demonstrated with a range of ketals of aromatic and aliphatic ketones. Extension to acetal substrates is also described, demonstrating the overall synthetic utility of this methodology for complex ether synthesis.