121464-75-3

Basic information

• Product Name: methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-(isopropylidenedioxy)propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate
• CAS NO: 121464-75-3
• Molecular Weight: 502.654
• Mol File: 121464-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-(isopropylidenedioxy)propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-(isopropylidenedioxy)propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(121464-75-3)
• EPA Substance Registry System: methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-(isopropylidenedioxy)propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(121464-75-3)

Safety Data

• Hazardous Substances Data: 121464-75-3(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 131703-67-8 (4R)-4-ethyl-4,5-dihydroxypentanal acetonide 
• 66859-22-1 methyl 1,2,3,4,5,6-hexahydroazepino<4,5-b>indole-5-carboxylate 
• 121464-74-2 (4S)-4-ethyl-4,5-dihydroxypentanal acetonide 
• 66859-30-1 methyl 3-benzyl-1,2,3,4,5,6-hexahydroazepino[4,5-b]indole-5-carboxylate 
• 121464-73-1 (2S)-2-ethyl-2-hydroxyhex-5-enol acetonide 
• 121464-72-0 (2S)-2-ethyl-2-hydroxyhex-5-enol 
• 121464-71-9 (R)-(2-ethoxyoxiran-2-yl)methanol 
• 4435-54-5 2-Methylene-1-butanol 
• 131703-70-3 (2R)-2-ethyl-2-hydroxyhex-5-enol acetonide 
• 131703-69-0 (2R)-2-ethyl-2-hydroxyhex-5-enol 
• 131703-68-9 (S)-(2-ethoxyoxiran-2-yl)methanol 

Downstream Products

• 121464-76-4 (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131829-80-6 (3aS,4S)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131829-72-6 (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131829-74-8 (3aS,4S)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131703-71-4 (3aR,4S,11bS)-3-Benzyl-6-chloro-4-[(S)-2-(toluene-4-sulfonyloxymethyl)-2-trimethylsilanyloxy-butyl]-2,3,3a,4,5,6-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 131703-71-4 (3aS,4R,11bR)-3-Benzyl-6-chloro-4-[(S)-2-(toluene-4-sulfonyloxymethyl)-2-trimethylsilanyloxy-butyl]-2,3,3a,4,5,6-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 131703-73-6 (7S,5R)-methyl 3-benzyl-1,2,3,4,5,6,7,8-octahydro-5-((2S)-2-ethyl-2,3-epoxypropyl)-7-(15-vindolinyl)azonino[5,4-b]indole-7-carboxylate 
• 131829-87-3 (7R,5S)-methyl 3-benzyl-1,2,3,4,5,6,7,8-octahydro-5-((2S)-2-ethyl-2,3-epoxypropyl)-7-(15-vindolinyl)azonino[5,4-b]indole-7-carboxylate 
• 121485-40-3 (7S,5R)-methyl 3-benzyl-1,2,3,4,5,6,7,8-octahydro-5-<(2S)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate 
• 121485-40-3 (7R,5S)-methyl 3-benzyl-1,2,3,4,5,6,7,8-octahydro-5-<(2S)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate 
• 131703-72-5 C₆₃H₇₈N₄O₁₂SSi 
• 131703-72-5 C₆₃H₇₈N₄O₁₂SSi 
• 131829-78-2 (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2S)-2-ethyl-2-hydroxy-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131829-81-7 (3aS,4S,11bR)-3-Benzyl-4-[(S)-2-hydroxy-2-(toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 

Relevant articles and documents

Enantioselective Syntheses of Vinblastine, Leurosidine, Vincovaline, and 20'-epi-Vincovaline

The binary indole-indoline alkaloids vinblastine (1), leurosidine (13), 20'-epi-vincovaline (14a), and vincovaline (14b) were obtained by coupling of vindoline (3) to the tetracyclic intermediates 7a, 7b or 22a, 22b, followed by reduction and cyclization