121511-54-4Relevant articles and documents
Synthesis, Structure, and Properties of Triple-Layered Naphthalenophane
Otsubo, Tetsuo,Aso, Yoshio,Ogura, Fumio,Misumi, Soichi,Kawamoto, Atsushi,Tanaka, Jiro
, p. 164 - 170 (2007/10/02)
The title compound was synthesized in a similar manner to a simple access to triple-layered paracyclophane.Its structure was elucidated by X-ray crystallographic analysis.The outer naphthalene rings are bent into a boat form and the inner naphthalene ring is bent into a twist form.These naphthalenes are stacked in layers within van der Waals contact.Therefore, there is a strong transannular ?-electronic interaction between them, which brings about characteristic bathochromism, hyperchromism, and broadening in the electronic spectrum.These effects are more prominent than those of the double-layered homologue.