1217189-55-3

Basic information

• Product Name: [(η4-C8H12)Rh(5-(4-nitrophenyl)dipyrromethene(1-))]
• CAS NO: 1217189-55-3
• Molecular Weight: 475.352
• Mol File: 1217189-55-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η4-C8H12)Rh(5-(4-nitrophenyl)dipyrromethene(1-))](CAS DataBase Reference)
• NIST Chemistry Reference: [(η4-C8H12)Rh(5-(4-nitrophenyl)dipyrromethene(1-))](1217189-55-3)
• EPA Substance Registry System: [(η4-C8H12)Rh(5-(4-nitrophenyl)dipyrromethene(1-))](1217189-55-3)

Safety Data

• Hazardous Substances Data: 1217189-55-3(Hazardous Substances Data)

Upstream product

• 143859-77-2 2,2'-[(4-nitrophenyl)methylene]bis(1H-pyrrole) 

Relevant articles and documents

Heteroleptic rhodium complexes containing both the dipyrrin/cyclooctadiene ligands and application of [(η4-C8H12)Rh(4-pyrdpm)] in the construction of homo-/hetero-bimetallic complexes

Heteroleptic rhodium(I) complexes with the general formulations [(η4-C8H12)Rh(L)] [η4-C8H12 = 1,5-cyclooctadiene; L = 5-(4-cyanophenyl)dipyrromethene, cydpm; 5-(4-nitrophenyl)dipyrromethene, ndpm; and 5-(4-benzyloxyphenyl)dipyrromethene, bdpm; 5-(4-pyridyl)dipyrromethene, 4-pyrdpm; 5-(3-pyridyl)dipyrromethene, 3-pyrdpm] have been synthesized. The complex [(η4-C8H12)Rh(4-pyrdpm)] have been used as a synthon in the construction of homo-bimetallic complex [(η4-C8H12)Rh(μ-4-pyrdpm)Rh(η5-C5Me5)Cl2] and hetero-bimetallic complexes [(η4-C8H12)Rh(μ-4-pyrdpm)Ir(η5-C5Me5)Cl2], [(η4-C8H12)Rh(μ-4-pyrdpm)Ru(η6-C10H14)Cl2] and [(η4-C8H12)Rh(μ-4-pyrdpm)Ru(η6-C6H6)Cl2]. Resulting complexes have been characterized by elemental analyses and spectral studies. Molecular structures of the representative mononuclear complexes [(η4-C8H12)Rh(ndpm)] and [(η4-C8H12)Rh(4-pyrdpm)] have been authenticated crystallographically.