122293-92-9Relevant articles and documents
Additions of Chiral Allyltitanocenes to Aldehydes: Diastereoselective Synthesis of Homoallylic Alcohols with a Recyclable Chiral Transition Metal Reagent
Collins, Scott,Kuntz, Bradley A.,Hong, Yaping
, p. 4154 - 4158 (2007/10/02)
Homochiral allyl- and crotyltitanocenes 4a (R = H) and 4b (R = Me) prepared from ansa-titanocene dichloride 2 react with aldehydes to provide on workup homoallylic alcohols 5 in excellent yield and with moderate to excellent anti diastereoselectivity in t