12267-07-1

Basic information

• Product Name: (η5-C5H4(COPh))Re(CO)3
• CAS NO: 12267-07-1
• Molecular Weight: 439.441
• Mol File: 12267-07-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (η5-C5H4(COPh))Re(CO)3(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-C5H4(COPh))Re(CO)3(12267-07-1)
• EPA Substance Registry System: (η5-C5H4(COPh))Re(CO)3(12267-07-1)

Safety Data

• Hazardous Substances Data: 12267-07-1(Hazardous Substances Data)

Upstream product

• 14220-21-4 rhenium(I) pentacarbonyl bromide 
• 98-88-4 benzoyl chloride 

Relevant articles and documents

A facile synthetic route to (η5-benzoylcyclopentadienyl)metal compounds

A reaction between cyclopentadienylsodium and ethyl benzoate in refluxing THF produces (benzoylcyclopentadienyl)sodium (4) in 70-80percent yield.Subsequent treatment of 4 in ethanol solution with thallium ethoxide affords (benzoylcyclopentadienyl)thallium (3) in nearly quantitative yield.Reactions of 3 with Mn(CO)5Br, Re(CO)5Br, 2 or FeCl2 lead to the respective η5-benzoylcyclopentadienyl derivatives of these metals, and demonstrate the utility of 3 in organometallic syntheses.Reactions of several of these organometallic ketones with cymantrenyllithium5-C5H4Li)Mn(CO)3> provide a useful new route to bimetallic compounds.