122908-32-1

Basic information

• Product Name: 3,6,6-Trimethoxy-1-methyl-3-phenylcyclohexa-1,4-diene
• CAS NO: 122908-32-1
• Molecular Weight: 260.333
• Mol File: 122908-32-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,6,6-Trimethoxy-1-methyl-3-phenylcyclohexa-1,4-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6,6-Trimethoxy-1-methyl-3-phenylcyclohexa-1,4-diene(122908-32-1)
• EPA Substance Registry System: 3,6,6-Trimethoxy-1-methyl-3-phenylcyclohexa-1,4-diene(122908-32-1)

Safety Data

• Hazardous Substances Data: 122908-32-1(Hazardous Substances Data)

Upstream product

• 643-93-6 3-methylbiphenyl 
• 124-41-4 sodium methylate 
• 67-56-1 methanol 

Downstream Products

• 122908-34-3 4-Methoxy-2-methyl-4-phenylcyclohexa-2,5-dienone 

Relevant articles and documents

SYNTHESIS OF PHENYL SUBSTITUTED CYCLOHEXA-1,4-DIENES AND CYCLOHEXA-2,5-DIENONES BY ANODIC METHOXYLATION OF ALKYLBIPHENYLS

The anodic methoxylation of a series of alkylbiphenyls (2-, 3-, 4-methylbiphenyl, 3,3'-, 4,4'-dimethylbiphenyl, 4-ethylbiphenyl and 4,4'-di-tert-butylbiphenyl) carried out under constant current intensity afforded, in a process of two electrons, a number of cis/trans cyclohexa-1,4-dienes and, in a process of four electrons, a number of cyclohexa-2,5-dienones after acidic hydrolysis of the corresponding cyclohexa-1,4-diene ketals.In some cases, side-chain substitution products were also obtained.Probable mechanisms are proposed.