123464-38-0

Basic information

• Product Name: Benzene, (1-cyclohexyl-2-nitroethyl)-
• CAS NO: 123464-38-0
• Molecular Formula: C14H19NO2
• Molecular Weight: 233.31
• Mol File: 123464-38-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, (1-cyclohexyl-2-nitroethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-cyclohexyl-2-nitroethyl)-(123464-38-0)
• EPA Substance Registry System: Benzene, (1-cyclohexyl-2-nitroethyl)-(123464-38-0)

Safety Data

• Hazardous Substances Data: 123464-38-0(Hazardous Substances Data)

Upstream product

• 780-69-8 triethoxyphenylsilane 
• 50598-92-0 (E)-(2-nitrovinyl)cyclohexane 
• 595-90-4 tetraphenyltin(IV) 
• 50598-92-0 2-cyclohexyl-1-nitroethene 
• 98-80-6 phenylboronic acid 
• 626-62-0 Cyclohexyl iodide 
• 102-96-5 (2-nitroethenyl)benzene 
• 5153-67-3 nitrostyrene 
• 1135-99-5 diphenyltin(IV) dichloride 

Relevant articles and documents

Deoxycholic acid-derived biaryl phosphites as versatile and enantioselective ligands in the rhodium-catalyzed conjugate addition of arylboronic acids to nitroalkenes

A highly enantioselective conjugate addition of arylboronic acids to cyclic as well as acyclic aromatic and aliphatic nitroalkenes is presented. The rhodium complexes obtained from deoxycholic acid-derived binaphthyl and flexible biphenyl phosphites showed good activity as well as very high enantioselectivity (ee up to 99%) in the conjugated addition even in the presence of challenging substrates such as 1-nitrocyclohexene or aliphatic acyclic nitroalkenes. Copyright

Palladium(II)-catalyzed Michael-type hydroarylation of nitroalkenes using aryltins and sodium tetraarylborates

A variety of aryltin compounds and sodium tetraarylborates can be employed for Michael-type hydroarylation reactions of nitroalkenes to afford β-arylnitroalkanes in moderate to good yields in the presence of either LiCl, MgCl2, or CaCl2 and a catalytic amount of palladium(II) salt (0.05 molar amount) in acetic acid. Results show that 50-70% of aryl groups out of all in these aryl compounds can be transferred to the products in this hydroarylation. The addition of a catalytic amount (0.05-0.10 molar amount) of a Lewis acid chloride, BiCl3 or SbCl3, much improves the product yield in some cases.

Conjugate addition of mixed diorganozinc compounds and functionalized organozinc cuprates to nitroolefins

equation presented The copper-catalyzed conjugate addition of symmetrical and mixed diorganozinc compounds as well as functionalized diorganozinc cuprates to nitroolefins leads to synthetically versatile nitro compounds in moderate to good yields. Mixed TMSM-organozinc compounds are suitable reagents for conjugate addition, since the TMSM group is not being transferred. Ipso substitution is observed in the absence of a catalytic amount of copper(I) salt. The nitroalkene moiety in 3-nitroacrylates proved to be the predominant Michael acceptor.