1236046-50-6

Basic information

• Product Name: (2-bromophenyl)(2-(pyridin-2-yl)phenyl)methanone
• Synonyms: (2-bromophenyl)(2-(pyridin-2-yl)phenyl)methanone
• CAS NO: 1236046-50-6
• Molecular Weight: 338.203
• Mol File: 1236046-50-6.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (2-bromophenyl)(2-(pyridin-2-yl)phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-bromophenyl)(2-(pyridin-2-yl)phenyl)methanone(1236046-50-6)
• EPA Substance Registry System: (2-bromophenyl)(2-(pyridin-2-yl)phenyl)methanone(1236046-50-6)

Safety Data

• Hazardous Substances Data: 1236046-50-6(Hazardous Substances Data)

Upstream product

• 1008-89-5 2-phenylpyridine 
• 26767-16-8 2-(2-bromophenyl)-2-oxoacetic acid 
• 2142-69-0 2-bromophenyl methyl ketone 
• 98-80-6 phenylboronic acid 
• 109-04-6 2-bromo-pyridine 
• 6630-33-7 ortho-bromobenzaldehyde 
• 18982-54-2 o-bromobenzyl alcohol 
• 95-46-5 2-methylphenyl bromide 
• 7157-15-5 2-bromomandelic acid 
• 88-65-3 2-bromobenzoic-acid 

Relevant articles and documents

Rhodium-Catalyzed Aryl Migratory/Decarbonylation of Diaryl Ketones via the Activation of Unstrained C-C Bonds

A Rh-catalyzed aryl migratory/decarbonylation of unstrained ketones has been developed. This viable transformation provides a complementary decarbonylative method using diaryl ketones to afford a variety of alkenylated heterocycles in good yields with moderate to good stereoselectivity and broad substrate scope. The synthetic utility of this protocol is also demonstrated by the conversion of the alkenylated heterocycles to tetrahydrocarbazole derivatives.

Polystyrene supported Dichloro-(8-aminoquinoline)-Palladium(II) complex catalyzed C[sbnd]H bond activation for ortho-acylation of 2-aryl pyridines

Polystyrene-supported Dichloro-(8-aminoquinoline)-Pd(II) complex C was synthesized and its catalytic efficiency was evaluated for ortho-acylation of 2-aryl pyridines with alcohols to form aryl ketones via cross dehydrogenative coupling. In addition in the presence of Pd(II) complex, toluene derivatives were also employed as an effective coupling partner for synthesis of aromatic ketones. Furthermore, this catalyst was highly stable and could be easily recovered by simple filtration and reused for four cycles with no significant decrease in its activity and selectivity.

Recyclable Pd(II)complex catalyzed oxidative sp2C[sbnd]H bond acylation of 2-aryl pyridines with toluene derivatives

A recyclable polymer–anchored Pd(II) complex C was synthesized and characterized using different spectroscopic techniques. In addition the catalytic efficiency of the Pd (II) complex C was evaluated for ortho-acylation of 2-aryl pyridines with toluene derivatives to form aryl ketones via cross dehydrogenative coupling. In this catalytic process toluene acts as an effective coupling partner upon sp3C[sbnd]H bond oxidation for sp2C[sbnd]H bond acylation of 2-aryl pyridines in the presence of Pd(II)/TBHP system on water. Furthermore, the catalyst C was highly stable and could be easily recovered and reused for four cycles with no significant decrease in its activity and selectivity.