123773-64-8

Basic information

• Product Name: phenyl 2-benzoxazolyl thioether
• Synonyms: phenyl 2-benzoxazolyl thioether
• CAS NO: 123773-64-8
• Molecular Weight: 227.287
• Mol File: 123773-64-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: phenyl 2-benzoxazolyl thioether(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl 2-benzoxazolyl thioether(123773-64-8)
• EPA Substance Registry System: phenyl 2-benzoxazolyl thioether(123773-64-8)

Safety Data

• Hazardous Substances Data: 123773-64-8(Hazardous Substances Data)

Upstream product

• 100-63-0 phenylhydrazine 
• 2382-96-9 2-sulfanyl-1,3-benzoxazole 
• 59-88-1 phenylhydrazine hydrochloride 
• 591-50-4 iodobenzene 
• 108-86-1 bromobenzene 
• 38111-44-3 phenylzinc(II) bromide 
• 98555-60-3 2-benzoxazolesulfenyl chloride 
• 108-98-5 thiophenol 
• 273-53-0 benzoxazole 
• 59919-11-8 2-methyl-1-phenyl-2-(phenylthio)propan-1-one 
• 882-33-7 diphenyldisulfane 
• 615-18-9 2-chloro-1,3-benzoxazole 
• 930-69-8 sodium thiophenolate 
• 95-56-7 2-hydroxybromobenzene 

Downstream Products

• 273-53-0 benzoxazole 
• 28403-86-3 1-phenyl-2-(phenylthio)propan-1-one 
• 2008-07-3 2-benzyl-1,3-benzoxazole 
• 884-09-3 phenyl thiobenzoate 

Relevant articles and documents

C[sbnd]S cross-coupling catalyzed by a series of easily accessible, well defined Ni(II) complexes of the type [(NHC)Ni(Cp)(Br)]

The synthesis, characterization and catalytic evaluation of a series of NHC-Ni(II) complexes 1-Ni (-Me), 2-Ni (-nBu) and 3-Ni (-Bn) bearing a phthalimide fragment and a cyclopentadienyl (Cp) ligand is reported. The complexes were evaluated in C

Visible-Light-Mediated Synthesis of Unsymmetrical Diaryl Sulfides via Oxidative Coupling of Arylhydrazine with Thiol

A metal-free visible-light-promoted oxidative coupling between thiols and arylhydrazines has been developed to afford diaryl sulfides using a catalytic amount of rose bengal as photocatalyst under aerobic conditions. A library of unsymmetrical diaryl sulfides with broad functionalities was synthesized in good yields at room temperature. The present methodology is also applicable to benzo[d]thiazole-2-thiols, benzo[d]oxazole-2-thiol, 1H-benzo[d]imidazole-2-thiols, and 1H-imidazole-2-thiol.

Selective: S -arylation of 2-oxazolidinethiones and selective N -arylation of 2-benzoxazolinones/2-benzimidazolinones

There exist three possible patterns for the reaction of cyclic 2-oxazolidinethione and 2-benzoxazolidinethione with arynes, namely (a) S-arylation, (b) N-arylation, and (c) aryne insertion into the thiocarbonyl group (CS). Our studies demonstrate that S-arylation wins out affording S-aryl dihydrooxazoles. In contrast, for related reactions of cyclic 2-benzoxazolinone and 2-benzimidazolinone with arynes, it is found that N-arylation outcompetes O-arylation and aryne insertion into the CO group to give N-aryl 2-benzoxazolinones and N-aryl 2-benzimidazolinones.