1237762-58-1Relevant articles and documents
Quinoneimido complexes of a metalloporphyrin: Isolation, X-ray crystal structures, and DFT calculations
Tsui, Wai-Man,Huang, Jie-Sheng,Tong, Glenna So Ming,Kui, Steven C. F.,Che, Chi-Ming,Zhu, Nianyong
supporting information; experimental part, p. 759 - 763 (2010/07/07)
Terminal quinoneimido complexes [RuIV (por) (NQu)(X)] (X=OEt: 1, OH: 2) were formed from the reaction of [Ru VI(por)O2] with 2,6-dimethylaniline. The X-ray crystal structures of 1 feature Ru-N(quinoneimido) bond lengths of 1.787(7)-1.80(2). Reaction of 2 with N-phenyl-benzene-1,4-diamine afforded bis(quinoneimido) complex [Ru(por) (NQu) (NQu')]. DFT calculations on 3 and 4 revealed a significant effect of 'Ru doping' on the oligoaniline structure.