124838-73-9

Basic information

• Product Name: (S)-1-Hexyl-3-hydroxy-1-azonia-bicyclo[2.2.2]octane; bromide
• Synonyms: (S)-1-Hexyl-3-hydroxy-1-azonia-bicyclo[2.2.2]octane; bromide
• CAS NO: 124838-73-9
• Molecular Weight: 292.26
• Mol File: 124838-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-1-Hexyl-3-hydroxy-1-azonia-bicyclo[2.2.2]octane; bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-1-Hexyl-3-hydroxy-1-azonia-bicyclo[2.2.2]octane; bromide(124838-73-9)
• EPA Substance Registry System: (S)-1-Hexyl-3-hydroxy-1-azonia-bicyclo[2.2.2]octane; bromide(124838-73-9)

Safety Data

• Hazardous Substances Data: 124838-73-9(Hazardous Substances Data)

Upstream product

• 111-25-1 1-bromo-hexane 
• 3684-26-2 (S)-quinuclidin-3-ol 

Relevant articles and documents

CHIRAL COMPLEX-FORMING AGENTS AND TRANS-PHASE TRANSFER AGENTS. 5. 3S-HYDROXY-1-ALKYLQUINUCLIDINIUM SALTS AND THEIR PROPERTIES.

Synthesized 3-hydroxy- and 3-benzyloxy-1-benzylquinuclidinium salts are in their catalytic activity comparable to benzyl(triethyl)ammonium chloride and are inferior to catalysts of the tetraalkylammonium type.The asymmetry-induced capability of chiral 3-hydroxy-1-alkylquinuclidinium salts is considerably inferior to the asymmetry-induced capability of the conformationally mobile N-benzylquininium chloride, which indicates the dependence of the asymmetric induction on the possibility of the approach of the β-hydroxylic group and the ammonium center of the catalyst in the transition state of the reaction.