124851-55-4

Basic information

• Product Name: (1S,5R)-3-Oxo-1-phenyl-8-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester
• CAS NO: 124851-55-4
• Molecular Weight: 260.29
• Mol File: 124851-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,5R)-3-Oxo-1-phenyl-8-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,5R)-3-Oxo-1-phenyl-8-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester(124851-55-4)
• EPA Substance Registry System: (1S,5R)-3-Oxo-1-phenyl-8-oxa-bicyclo[3.2.1]octane-2-carboxylic acid methyl ester(124851-55-4)

Safety Data

• Hazardous Substances Data: 124851-55-4(Hazardous Substances Data)

Upstream product

• 56139-59-4 4-oxo-4-phenyl-butyraldehyde 
• 74590-73-1 1,3-bis(trimethylsiloxy)-1-methoxybuta-1,3-diene 

Relevant articles and documents

BIS(TRIMETHYLSILYL) ENOL AS 1,3-DIANON EQUIVALENTS: REGIOCONTROLLED AND ANNULATION REACTIONS

In the presence of titanium tetrachloride, 1,3-bis(trimethoxysiloxy)-1-methoxy-1,3-butadiene (1) undergoes facile annulation reactions with 1,4 -and 1,5-dielectrophiles to generate seven- and eight-membered bicyclic ether adducts.The annulations occur in good yields (49-83percent) and are also highly regioselective for substrates containing two distinct electrophilic groups.