124992-51-4Relevant articles and documents
Stereoselective Reductions of 2-Keto Sulfoxides with Hydrides
Carreno, M. Carmen,Ruano, Jose L. Garcia,Martin, Ana M.,Pedregal, Concepcion,Rodriguez, Jesus H.,et al.
, p. 2120 - 2128 (1990)
The results of reductions of some acyclic 2-keto sulfoxides (ArC(O)CH2S(O)R; Ar=Ph, 2-Py, 4-Py, and R=Me, p-Tol) and flexible and rigid 2-sulfinylcyclohexanone diastereomers with various metal hydrides are reported.The configurational assignment and confo