1251034-28-2

Basic information

• Product Name: 4,4'-bis{p-[2-(perfluorohexyl)ethyl]phenyl}-2,2'-bipyridine
• Synonyms: 4,4'-bis{p-[2-(perfluorohexyl)ethyl]phenyl}-2,2'-bipyridine
• CAS NO: 1251034-28-2
• Molecular Weight: 1000.56
• Mol File: 1251034-28-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4'-bis{p-[2-(perfluorohexyl)ethyl]phenyl}-2,2'-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-bis{p-[2-(perfluorohexyl)ethyl]phenyl}-2,2'-bipyridine(1251034-28-2)
• EPA Substance Registry System: 4,4'-bis{p-[2-(perfluorohexyl)ethyl]phenyl}-2,2'-bipyridine(1251034-28-2)

Safety Data

• Hazardous Substances Data: 1251034-28-2(Hazardous Substances Data)

Upstream product

• 18511-71-2 4,4'-dibromo-2,2'-bipyridine 
• 1251034-29-3 p-[2-(perfluorohexyl)ethyl]phenylboronic acid 

Relevant articles and documents

Synthesis of new CO2-soluble ruthenium(II) and cobalt(II) polypyridine complexes bearing fluorinated alkyl chains and their application to photoreduction of liq. CO2

Eight types of new CO2-soluble or CO2-philic ruthenium(II) and cobalt(II) polypyridine complexes, namely, [M(F84OPh) 3](BArF)2, [M(F44OPh)3](BArF)2, [M(F62Ph)3](BArF)2, and [M(F62O)3](BArF) 2 (M = Ru or Co, BArF: tetrakis[3,5-bis(trifluoromethyl)phenyl] borate), were prepared from bipyridine derivatives bearing highly fluorinated alkyl chains and applied to the photoreduction of liq. CO2 under a high pressure of 6.8 MPa at 35 °C. All these complexes have higher philicity toward liq. CO2 than the corresponding complexes with PF 6- as the counteranion. Using the Ru(II)-Co(II) systems of [M(F44OPh)3](BArF)2 and [M(F62O)3](BArF) 2, direct photoreduction of CO2 was achieved without the use of any organic solvent.