1264712-17-5

Basic information

• Product Name: 1-(2-fluorophenyl)naphthalen-2-ol
• Synonyms: 1-(2-fluorophenyl)naphthalen-2-ol
• CAS NO: 1264712-17-5
• Molecular Weight: 238.261
• Mol File: 1264712-17-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(2-fluorophenyl)naphthalen-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-fluorophenyl)naphthalen-2-ol(1264712-17-5)
• EPA Substance Registry System: 1-(2-fluorophenyl)naphthalen-2-ol(1264712-17-5)

Safety Data

• Hazardous Substances Data: 1264712-17-5(Hazardous Substances Data)

Upstream product

• 135-19-3 β-naphthol 
• 573-97-7 1-bromo-2-naphthol 
• 1993-03-9 o-fluorophenylboronic acid 
• 1382763-56-5 1-(2-fluorophenyl)-2-methoxynaphthalene 
• 1264712-16-4 2-[1-(2-fluoro-phenyl)naphthalen-2-yloxy]tetrahydropyran 

Downstream Products

• 1264712-19-7 3-[1-(2-fluorophenyl)naphthalen-2-ylsulfanyl]propionic acid ethyl ester 
• 205-43-6 Benzo[b]naphtho[1,2-d]thiophene 
• 1264712-18-6 trifluoromethanesulfonic acid 1-(2-fluoro-phenyl)naphthalen-2-yl ester 
• 1383607-08-6 6-phenylbenzo[b]naphtho[1,2-d]furan 
• 1382763-43-0 6-[3-(9,10-diphenyl-2-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan 
• 1382763-47-4 6-[4-(9,10-diphenyl-2-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan 
• 1382763-49-6 6-[4-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan 
• 205-39-0 benzo[b]naphtho[1,2-d]furan 
• 1382763-45-2 6-[3-(10-phenyl-9-anthryl)phenyl]-benzo[b]naphtho[1,2-d]furan 

Relevant articles and documents

Transition-Metal-Free Aryl–Aryl Cross-Coupling: C?H Arylation of 2-Naphthols with Diaryliodonium Salts

Transition-metal-free regioselecitive C?H arylation of 2-naphthols with diaryliodonium salts has been developed. The reaction proceeds under very simple experimental conditions and affords a range of products with various substitution patterns. The method allows for the incorporation of electron-deficient aryls, which complements well currently existing metal-free aryl–aryl cross-couplings of phenols that have been so far restricted to the introduction of electron-rich aryl moieties. The mechanism of the reaction was studied by means of DFT calculations, demonstrating that the C?C bond formation occurs via a dearomatization of 2-naphthol substrate, followed by a subsequent rearomatization by tautomerization. The computations show that the use of a low polarity solvent and an insoluble inorganic base is key to securing the high selectivity of the C?C coupling over a competing C?O arylation pathway, by preventing the incipient deprotonation of 2-naphthol.

Organoboron Compound and Method for Manufacturing the Same

To provide a novel organoboron compound which is useful as a reactant of organic synthesis. To provide a method for manufacturing the organoboron compound. A novel organoboron compound represented by General Formula (G1) below is provided. Note that in General Formula (G1), R1 to R9 separately represent any one of hydrogen, an alkyl group having 1 to 6 carbon atoms, and an aryl group having 6 to 16 carbon atoms. R10 and R11 separately represent hydrogen or an alkyl group having 1 to 6 carbon atoms, and R10 and R11 may be bonded with each other to form a ring. Further, X represents an oxygen atom or a sulfur atom.

Synthesis of functionalized dibenzothiophenes- An efficient three-step approach based on Pd-catalyzed C-C and C-S bond formations

A novel and efficient three-step protocol for synthesizing functionalized dibenzothiophenes (DBTs) from common starting materials and by using palladium-catalyzed carbon-carbon and carbon-sulfur bond formations is presented. The reaction conditions offer significantly improved functional-group tolerance and regioselectivity as compared to previously reported methods. A flexible and concise three-step protocol for the synthesis of functionalized dibenzothiophenes DBTs from readily available starting materials is presented. The method is based on two palladium-catalyzed reactions to prepare the masked thiophenols 4followed by deprotection and in situ cyclization to form the DBT skeleton. This approach offers improved functional-group tolerance as well as regiocontrol in the synthesis of functionalized DBTs as compared to previously reported methods.