1264932-10-6

Basic information

• Product Name: ethyl 9,11-dioxo-10-(m-tolyl)-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-8-carboxylate
• Synonyms: ethyl 9,11-dioxo-10-(m-tolyl)-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-8-carboxylate
• CAS NO: 1264932-10-6
• Molecular Weight: 400.434
• Mol File: 1264932-10-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl 9,11-dioxo-10-(m-tolyl)-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-8-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 9,11-dioxo-10-(m-tolyl)-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-8-carboxylate(1264932-10-6)
• EPA Substance Registry System: ethyl 9,11-dioxo-10-(m-tolyl)-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-8-carboxylate(1264932-10-6)

Safety Data

• Hazardous Substances Data: 1264932-10-6(Hazardous Substances Data)

Upstream product

• 20299-79-0 1-(3-methylphenyl)-1H-pyrrole-2,5-dione 
• 88014-09-9 (3,4-dihydro-1H-isoquinolin-2-yl)-acetic acid ethyl ester 

Relevant articles and documents

Building a Pyrazole–Benzothiadiazole–Pyrazole Photosensitizer into Metal–Organic Frameworks for Photocatalytic Aerobic Oxidation

Charge separation plays a crucial role in regulating photochemical properties and therefore warrants consideration in designing photocatalysts. Metal–organic frameworks (MOFs) are emerging as promising candidates for heterogeneous photocatalysis due to their structural designability and tunability of photon absorption. Herein, we report the design of a pyrazole–benzothiadiazole–pyrazole organic molecule bearing a donor–acceptor–donor conjugated π-system for fast charge separation. Further attempts to integrate such a photosensitizer into MOFs afford a more effective heterogeneous photocatalyst (JNU-204). Under visible-light irradiation, three aerobic oxidation reactions involving different oxygenation pathways were achieved on JNU-204. Recycling experiments were conducted to demonstrate the stability and reusability of JNU-204 as a robust heterogeneous photocatalyst. Furthermore, we illustrate its applications in the facile synthesis of pyrrolo[2,1-a]isoquinoline-containing heterocycles, core skeletons of a family of marine natural products. JNU-204 is an exemplary MOF platform with good photon absorption, suitable band gap, fast charge separation, and extraordinary chemical stability for proceeding with aerobic oxidation reactions under visible-light irradiation.

Pyrrole [2,1-a] isoquinoline alkaloid and preparation method and application thereof

The invention discloses pyrrole [2,1-a] isoquinoline alkaloid and a preparation method and medical application thereof, and belongs to the field of medicinal chemistry. The structural general formula of the pyrrole [2,1-a] isoquinoline alkaloid is as show