126745-09-3

Basic information

• Product Name: N'-[(S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N-methyl-N-((S)-1-phenyl-ethyl)-formamidine
• CAS NO: 126745-09-3
• Molecular Weight: 362.631
• Mol File: 126745-09-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N'-[(S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N-methyl-N-((S)-1-phenyl-ethyl)-formamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N'-[(S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N-methyl-N-((S)-1-phenyl-ethyl)-formamidine(126745-09-3)
• EPA Substance Registry System: N'-[(S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N-methyl-N-((S)-1-phenyl-ethyl)-formamidine(126745-09-3)

Safety Data

• Hazardous Substances Data: 126745-09-3(Hazardous Substances Data)

Upstream product

• 103-67-3 benzyl-methyl-amine 
• 19145-06-3 (S)-N-formyl-1-phenylethylamine 
• 92686-73-2 N'-[(S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N,N-dimethyl-formamidine 
• 2627-86-3 (S)-1-phenyl-ethylamine 
• 126745-06-0 N-Benzyl-N'-[(S)-1-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-propyl]-N-methyl-formamidine 
• 74-88-4 methyl iodide 
• 19131-99-8 N-methyl-N-[(S)-1-phenylethyl]amine 
• 6948-01-2 (R)-(+)-α-methylbenzyl formamide 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 5933-40-4 (R)-(+)-N,α-dimethylbenzylamine 

Relevant articles and documents

Stereoselective α-Methylation of N-Methyl Benzylamine via a Combination of Chromium Tricarbonyl and Chiral Formamidine Methodologies.

Whereas carbanions of formamidines derived from N-methyl benzylamine and L-valinol or L-leucinol undergo electrophilic benzylic methylation with poor stereoselectivities (d.e. 17-26percent), enhanced stereoselectivities (d.e. 74-84percent) are observed for the corresponding chromium tricarbonyl complexes.