126745-48-0Relevant articles and documents
Convenient Synthesis of Alkylhydrazides by the Cobalt-Catalyzed Hydrohydrazination Reaction of Olefins and Azodicarboxylates
Waser, Jerome,Carreira, Erick M.
, p. 5676 - 5677 (2004)
Treatment of olefins 2 with 1.5 equiv of di-tert-butyl azodicarboxylate (3), 1 equiv of PhSiH3, and 1.5-5 mol % of the simple Co(III) catalyst 1 in ethanol at 23 °C affords the Markovnikov hydrazide product for a broad range of olefins in 62-94% yield. Copyright
MITSUNOBU REACTIONS OF N-ALKYL AND N-ACYL SULFONAMIDES - AN EFFICIENT ROUTE TO PROTECTED AMINES
Henry, James R.,Marcin, Lawrence R.,McIntosh, Matthias C.,Scola, Paul M.,Harris, G. Davis,Weinreb, Steven M.
, p. 5709 - 5712 (2007/10/02)
N-Methyl p-toluenesulfonamide and N-BOC p-toluenesulfonamide can be directly coupled with primary or secundary alcohols under Mitsunobu conditions to afford various sulfonamide-protected amines.