12701-34-7Relevant articles and documents
ELECTROCHEMICAL STUDIES OF ORGANOMETALLIC COMPOUNDS I. ON THE REVERSIBILITY OF THE FIRST REDUCTION STAGE OF TITANOCENE DICHLORIDE
Mugnier, Y.,Moise, C.,Laviron, E.
, p. 61 - 66 (1981)
The 1e reduction of titanocene dichloride (η5-Cp2TiCl2) in various solvents has been examined in detail by polarography, voltammetry on a disk electrode, and linear potential sweep voltammetry.In all cases, the electron uptake is followed by a fast loss of Cl-, which is replaced by a neutral ligand (which can be a solvent molecule).In tetrahydrofuran, whose binding ability is weak, a pseudo reversible behaviour is observed due to a return of Cl- to the molecule.In dimethylformamide, which is strongly bonded, the reaction is irreversible.In pyridine, it can be reversible or irreversible according to the conditions.