1272029-49-8

Basic information

• Product Name: 2-(2',6'-difluorophenyl)-1,10-phenanthroline
• CAS NO: 1272029-49-8
• Molecular Weight: 292.288
• Mol File: 1272029-49-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2',6'-difluorophenyl)-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2',6'-difluorophenyl)-1,10-phenanthroline(1272029-49-8)
• EPA Substance Registry System: 2-(2',6'-difluorophenyl)-1,10-phenanthroline(1272029-49-8)

Safety Data

• Hazardous Substances Data: 1272029-49-8(Hazardous Substances Data)

Upstream product

• 13670-99-0 2,6-difluoroacetophenone 
• 158753-17-4 8-amino-7-quinolinecarbaldehyde 

Downstream Products

• 1272029-60-3 [(2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(NCCH₃)Cl][OTf] 

Relevant articles and documents

Oxidatively resistant ligands for palladium-catalyzed aerobic alcohol oxidation

The complex [(neocuproine)Pd(OAc)]2[OTf]2 (1) catalyzes the aerobic oxidation of 2-heptanol at room temperature, but competitive ligand oxidation leads to low catalyst lifetimes. In an effort to mitigate the oxidative degradation of the ligand, a variety of Pd complexes ligated by fluorinated phenanthrolines (bis-2,9-(trifluoromethyl)-1,10- phenanthroline (btfm-phen), 4-methyl-2-(trifluoromethyl)-1,10-phenanthroline (tfmm-phen), and 2-(o-difluorophenyl)-1,10-phenanthroline (odfp-phen)) were prepared and tested. Active catalyst precursors were generated by in situ conproportionation of (N-N)Pd(OAc)2 and [(N-N)Pd(NCCH 3)2[OTf]2. Pd complexes derived from tfmm-phen catalyzed the aerobic oxidation of 2-heptanol at room temperature with up to 22 turnovers, nearly double that of 1.