127516-27-2Relevant articles and documents
Zirconium-catalyzed asymmetric carboalumination of alkenes: ZACA-lipase-catalyzed acetylation synergy
Huang, Zhihong,Tan, Ze,Novak, Tibor,Zhu, Gangguo,Negishi, Ei-Ichi
, p. 539 - 545 (2008/02/08)
ZACA-lipase-catalyzed acetylation tandem reactions provide highly efficient and selective routes to either (R)- or (S)-2-methyl-1-alkanols, making, for the first time, the ZACA-based asymmetric synthesis of 2-methyl-1-alkanols widely applicable and satisfactory.
THE TOTAL SYNTHESIS OF 10-(R,S)-C30 BOTRYOCOCCENE AND BOTRYOCOCCANE AND A NEW SYNTHESIS OF A GENERAL INTERMEDIATE TO THE BOTRYOCOCCENE FAMILY.
Hird, Nicholas W.,Lee, Thomas V.,Leigh, Alistair J.,Maxwell, James R.,Peakman, Torren M.
, p. 4867 - 4870 (2007/10/02)
The first synthesis of a C-30 botryococcene has been achieved by using a modified Julia reaction for the key coupling of fragments (2) and (3).The same strategy has been used in a new synthesis of a known synthetic precursor to the entire botryococcene family.