1275582-65-4

Basic information

• Product Name: 9-bromo-decane-1-ol
• Synonyms: 9-bromo-decane-1-ol
• CAS NO: 1275582-65-4
• Molecular Weight: 237.18
• Mol File: 1275582-65-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 9-bromo-decane-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 9-bromo-decane-1-ol(1275582-65-4)
• EPA Substance Registry System: 9-bromo-decane-1-ol(1275582-65-4)

Safety Data

• Hazardous Substances Data: 1275582-65-4(Hazardous Substances Data)

Upstream product

• 13019-22-2 9-Decen-1-ol 
• 100189-71-7 ((dec-9-en-1-yloxy)methyl)benzene 

Relevant articles and documents

Synthesis, structural characterization and catalytic activity of a multifunctional enzyme mimetic oxoperoxovanadium(v) complex

The synthesis and structural characterization of a novel oxoperoxovanadium(v) complex [VO(O2)(PAH)(phen)] containing the ligands 2-phenylacetohydroxamic acid (PAHH) and 1,10-phenanthroline (phen) has been accomplished. The oxoperoxovanadium(v) complex was found to mimic both vanadate-dependent haloperoxidase (VHPO) activity as well as nuclease activity through effective interaction with DNA. The complex is the first example of a structurally characterized stable oxoperoxovanadium(v) complex with a coordinated bi-dentate hydroximate moiety (-CONHO-) from 2-phenylacetohydroximate (PAH). The oxoperoxovanadium(v) complex has been used as catalyst for the peroxidative bromination reaction of some unsaturated alcohols (e.g. 4-pentene-1-ol, 1-octene-3-ol and 9-decene-1-ol) in the presence of H2O2 and KBr. The catalytic products have been characterized by GC-MS analysis and spectrophotometric methods. The DNA binding of this complex has been established with CT DNA whereas the DNA cleavage was demonstrated with plasmid DNA. The interactions of the complex with DNA have been monitored by electronic absorption and fluorescence emission spectroscopy. Viscometric measurements suggest that the compound is a DNA intercalator. The nuclease activity of this complex was confirmed by gel electrophoresis studies.

Cleavage of benzyl ethers by triphenylphosphine hydrobromide

Triphenylphosphine hydrobromide was found to cleave the benzyl ethers derived from 1°, 2° alkyl, and aryl alcohols to the corresponding alcohols and benzyltriphenylphosphonium bromide in good yields. Alkene and allyl phosphonium salts were produced from the benzyl ethers with 3° alkyl and allyl groups, respectively. These results indicate that the formation of the product is determined by the relative stability of the carbocationic intermediate. The anhydrous, stoichiometric amount of PPh3·HBr offers a new and effective method for the deprotection of benzyl ethers.