127677-14-9

Basic information

• Product Name: Dimethyl-[(S)-2-phenyl-2-((E)-1-trimethylsilanyloxy-propenyloxy)-ethyl]-amine
• CAS NO: 127677-14-9
• Molecular Weight: 293.481
• Mol File: 127677-14-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dimethyl-[(S)-2-phenyl-2-((E)-1-trimethylsilanyloxy-propenyloxy)-ethyl]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-[(S)-2-phenyl-2-((E)-1-trimethylsilanyloxy-propenyloxy)-ethyl]-amine(127677-14-9)
• EPA Substance Registry System: Dimethyl-[(S)-2-phenyl-2-((E)-1-trimethylsilanyloxy-propenyloxy)-ethyl]-amine(127677-14-9)

Safety Data

• Hazardous Substances Data: 127677-14-9(Hazardous Substances Data)

Upstream product

• 34469-10-8 (S)-2-(dimethylamino)-2-oxo-1-phenylethyl acetate 
• 51019-44-4 (S)-2-chloro-2-oxo-1-phenylethyl acetate 
• 2202-68-8 (S)-2-dimethylamino-1-phenylethanol 
• 7322-88-5 (S)-acetylmandelic acid 
• 17199-29-0 (S)-Mandelic acid 
• 75-77-4 chloro-trimethyl-silane 
• 127677-23-0 Propionic acid (S)-2-dimethylamino-1-phenyl-ethyl ester 

Relevant articles and documents

AUXILIARY SRTUCTURE AND ASYMMETRIC INDUCTION IN THE "MUKAIYAMA-ALDOL" REACTIONS OF CHIRAL SILYL KETENE ACETALS

A variety of chiral auxiliaries R*OH were prepared and tested for levels of asymmetric induction control in the "Mukaiyama-aldol" reaction of chiral silyl ketene acetals.Structural features required for high levels of control are discussed.