128806-39-3

Basic information

• Product Name: C₆₂H₄₆N₈O₁₀Se₂
• CAS NO: 128806-39-3
• Molecular Weight: 1221.01
• Mol File: 128806-39-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₆₂H₄₆N₈O₁₀Se₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₆₂H₄₆N₈O₁₀Se₂(128806-39-3)
• EPA Substance Registry System: C₆₂H₄₆N₈O₁₀Se₂(128806-39-3)

Safety Data

• Hazardous Substances Data: 128806-39-3(Hazardous Substances Data)

Upstream product

• 141874-31-9 Bis<(R)-(2'-amino-1,1'-binaphthalene)-2-yl> diselenide 
• 1655-55-6 1-(2,4-dinitro-phenyl)-L-proline 
• 128806-32-6 Bis<(R)-(2'-acetylamino-1,1'-binaphthalene)-2-yl> diselenide 
• 141874-27-3 (S)-1-(2,4-dinitrophenyl)prolyl chloride 

Downstream Products

• 128806-31-5 (S)-1-(2,4-Dinitro-phenyl)-pyrrolidine-2-carboxylic acid [2'-(2-methoxy-1-methyl-2-phenyl-ethylselanyl)-[1,1']binaphthalenyl-2-yl]-amide 

Relevant articles and documents

ASYMMETRIC TRANS-ADDITION REACTIONS USING CHIRAL SELENOBINAPHTHYLS

Asymmetric trans-addition reactions of (E)-phenylpropene, a mechanistically novel reaction, have been achieved by using chiral selenium-containing binaphthyl derivatives.Introduction of an amide group at 2'-position in the binaphthyl skeleton enhances considerably the diastereomeric excess (d.e.) of the asymmetric reaction presumably due to attractive interaction between the nitrogen lone pair and the seleniranium intermediate.Introduction of another chiral center in the amide group further enhances the d.e. as high as 79 percent, which is the highest asymmetric induction ever achieved in the asymmetric trans-addition reaction.