1296196-39-8

Basic information

• Product Name: (S)-2-(1-methyl-2-(2-phenylcyclohexylidene)hydrazinyl)pyridine
• CAS NO: 1296196-39-8
• Molecular Weight: 279.385
• Mol File: 1296196-39-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-2-(1-methyl-2-(2-phenylcyclohexylidene)hydrazinyl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-(1-methyl-2-(2-phenylcyclohexylidene)hydrazinyl)pyridine(1296196-39-8)
• EPA Substance Registry System: (S)-2-(1-methyl-2-(2-phenylcyclohexylidene)hydrazinyl)pyridine(1296196-39-8)

Safety Data

• Hazardous Substances Data: 1296196-39-8(Hazardous Substances Data)

Upstream product

• 98919-68-7 (1R,2S)-trans-2-phenylcyclohexanol 
• 4231-74-7 N-methyl-N-(pyridin-2-yl)hydrazine 
• 1444-65-1 (2S)-2-phenyl-1-cyclohexanone 
• 109-04-6 2-bromo-pyridine 

Relevant articles and documents

Rapid determination of enantiomeric excess of α-chiral cyclohexanones using circular dichroism spectroscopy

Chemical equations presented. Ketone handedness was discriminated using circular dichroism (CD) spectroscopy by monitoring the metal-to-ligand charge transfer (MLCT) bands of complexes between [CuI((S)-1)(CH 3CN)2]PF6 and derivatized α-chiral cyclohexanones (4). This method was able to quantify the enantiomeric excess of unknown samples using a calibration curve, giving an absolute error of ±7%. The analysis was fast, allowing potential application of this assay in high-throughput screening (HTS).