129905-39-1

Basic information

• Product Name: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylthio-α-D-glucopyranoside
• Synonyms: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylthio-α-D-glucopyranoside
• CAS NO: 129905-39-1
• Molecular Weight: 412.461
• Mol File: 129905-39-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylthio-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylthio-α-D-glucopyranoside(129905-39-1)
• EPA Substance Registry System: methyl 2,3,4-tri-O-acetyl-6-deoxy-6-phenylthio-α-D-glucopyranoside(129905-39-1)

Safety Data

• Hazardous Substances Data: 129905-39-1(Hazardous Substances Data)

Upstream product

• 882-33-7 diphenyldisulfane 
• 7404-32-2 methyl 2,3,4-tri-O-acetyl-6-bromo-6-deoxy-α-D-glucopyranoside 
• 108-98-5 thiophenol 
• 108-24-7 acetic anhydride 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 129905-38-0 methyl-6-S-phenyl-6-thio-α-D-glucopyranoside 
• 4144-87-0 methyl 6-chloro-6-deoxy-α-D-glucopyranoside 

Relevant articles and documents

Useful approach to the synthesis of aryl thio- and selenoglycosides in the presence of rongalite

A simple, mild, and cost effective methodology has been developed for the synthesis of aryl thio-and selenoglycosides from glycosyl halides and diaryl dichalcogenides. Diaryl dichalcogenides undergo reductive cleavage in the presence of rongalite (HOCH2SO2Na) to generate a chalcogenide anion in situ followed by reaction with glycosyl halides to furnish the corresponding aryl thio- and selenoglycosides in excellent yields. Using this protocol, synthesis of 4-methyl-7-thioumbelliferyl-β-d-cellobioside (MUS-CB), a fluorescent non-hydrolyzable substrate analogue for cellulases has been achieved.