130065-37-1Relevant articles and documents
Nickel-Catalyzed Regiodivergent Reductive Hydroarylation of Styrenes
Xue, Yuhang,Chen, Jian,Song, Peihong,He, Yuli,Zhu, Shaolin
supporting information, p. 1647 - 1651 (2021/07/02)
We report a ligand-controlled nickel-catalyzed reductive hydroarylation of styrenes with predictable and controllable regioselectivity. With a diamine ligand, the reaction produces selective linear hydroarylation products. Alternatively, with a chiral PyrOx ligand, branch-selective enantioenriched 1,1-diarylalkane products are obtained. Preliminary mechanistic results are consistent with a reductive Heck process.
Enantioselective Reductive Cross-Coupling of Aryl/Alkenyl Bromides with Benzylic Chlorides via Photoredox/Biimidazoline Nickel Dual Catalysis
Cheng, Xiaokai,Fang, Qun,Li, Tongtong,Lu, Jiamin,Lu, Zhan,Wang, Huifeng
supporting information, (2022/02/07)
The asymmetric reductive arylation and alkenylation of benzylic chloride under photoredox/nickel dual catalysis using chiral biimidazoline (BiIm) ligand is reported to access 1,1-diaryl alkanes and aryl allylic compounds with good yield as well as stereo-
Highly chemoselective and enantiospecific Suzuki-Miyaura cross-couplings of benzylic organoboronic esters
Glasspoole, Ben W.,Oderinde, Martins S.,Moore, Brandon D.,Antoft-Finch, Aurora,Crudden, Cathleen M.
, p. 1759 - 1763 (2013/07/26)
The use of potassium carbonate in addition to silver oxide is shown to increase the enantiospecificity of the Suzuki-Miyaura cross-coupling reaction of chiral secondary benzylic boronic esters. From mechanistic studies, it is shown that the reaction is co