13035-49-9

Basic information

• Product Name: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl iodide
• CAS NO: 13035-49-9
• Molecular Weight: 458.204
• Mol File: 13035-49-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl iodide(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl iodide(13035-49-9)
• EPA Substance Registry System: 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl iodide(13035-49-9)

Safety Data

• Hazardous Substances Data: 13035-49-9(Hazardous Substances Data)

Upstream product

• 3867-86-5 Brigl's anhydride 
• 108-24-7 acetic anhydride 

Downstream Products

• 31281-76-2 O-benzyl-2,3,4,6-tetra-O-acetyl-α-D-glucopyranoside 
• 247075-68-9 6-Fluoro-7-(4-methyl-piperazin-1-yl)-4-oxo-1-[4-((2S,3R,4S,5R,6R)-3,4,5-triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yloxy)-phenyl]-1,4-dihydro-quinoline-3-carboxylic acid ethyl ester 
• 1263182-13-3 C₃₈H₄₇NO₁₃S 
• 55094-26-3 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,4,6-tetra-O-benzyl-β-D-mannopyranosyl)-α-D-glucopyranoside 
• 55094-26-3 methyl 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl-(1→6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 3947-62-4 2,3,4,5-tetra-O-acetyl-D-glucopyranose 
• 3366-47-0 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose 
• 13036-15-2 1,3,4,6-tetra-O-acetyl-β-D-glucopyranose 
• 147577-25-1 allyl 2,3-di-O-acetyl-4,6-O-(4-methoxybenzylidene)-β-D-glucopyranoside 

Relevant articles and documents

Reaction of organocuprate reagents with protected 1,2-anhydro sugars. Stereocontrolled synthesis of 2-deoxy-C-glycosyl compounds

The reaction of protected 1,2-anhydro-α-D-gluco- and β-D-manno-pyranoses with alkyl and phenyl organocuprates afforded the corresponding C-glycosyl compounds in acceptable to high yield. Complete stereocontrol was obtained, leading respectively to the β-D or the α-D anomer. With the perbenzylated manno derivative, deoxygenation at C-2 was achieved in high yield, affording 2-deoxy-α-D-C-glycosyl compounds.