13046-51-0

Basic information

• Product Name: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(thiomethylene)]tetrakis-
• CAS NO: 13046-51-0
• Molecular Formula: C30H28S4
• Molecular Weight: 516.816
• Mol File: 13046-51-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(thiomethylene)]tetrakis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(thiomethylene)]tetrakis-(13046-51-0)
• EPA Substance Registry System: Benzene, 1,1',1'',1'''-[1,2-ethenediylidenetetrakis(thiomethylene)]tetrakis-(13046-51-0)

Safety Data

• Hazardous Substances Data: 13046-51-0(Hazardous Substances Data)

Upstream product

• 13046-49-6 (toluene-4-sulfonyl)-dithiocarbonohydrazonic acid dibenzyl ester 
• 26504-29-0 dibenzyl trithiocarbonate 
• 100-44-7 benzyl chloride 
• 13046-53-2 Tosyl-dithiocarbazinsaeurebenzylester 
• 98-88-4 benzoyl chloride 
• 68494-08-6 4,5-bis(benzoylthio)-1,3-dithiole-2-thione 
• 80733-35-3 Ditetraethylammoniumtetrathiooxalat 
• 68494-09-7 4,5-bis(benzoylthio)-1,3-dithiole-2-one 
• 54995-25-4 4,5-bis(benzylthio)-1,3-dithiole-2-thione 
• 64394-45-2 2,5-diketo-1,3,4,6-tetrathiapentalene 
• 7196-01-2 4-(1-phenylvinyl)morpholine 

Downstream Products

• 35345-26-7 Oxalsaeure-bisthiolbenzylester 

Relevant articles and documents

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Thiono- and dithioesters, XXXVI: Tetrakis(alkylthio)ethylenes

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Electrochemical Synthesis of Tetrathioethylenes

Electrochemical reduction of 4,5-bis(alkylthio)-1,3-dithiol-2-ones (1a-d) in aprotic medium, followed by alkylation, gives tetrathioethylenes (2) in nearly quantitative yield.A similar reduction and alkylation of 1,3,4,6-tetrathiapentalene-2,5-dione (3) leads to 1 in almost quantitative yield. 4,5-Bis(alkylthio)-1,3-dithiole-2-thiones (4) gives tetrathiooethylenes under similar conditions in lower yield than 1.The mechanism of the reactions is discussed on the basis of the preparative and cyclic voltammetric results.