13059-89-7Relevant articles and documents
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Brady,Cropper
, p. 507,514,515 (1950)
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Peculiarities of the interaction of dinitrobenzenes with t-BuNHMgBr and t-BuNHLi
Apasov, E. T.,Dzhetigenov, B. A.,Shepelev, E. V.,Strelenko, Yu. A.,Kalinin, A. V.
, p. 703 - 706 (2007/10/02)
Reactions of m- and p-dinitrobenzenes with t-BuNHMgBr and t-BuNHLi were studied.The reactions afford azo- and azoxy-derivatives and products of nucleophilic substitution.
The Stabilities of Meisenheimer Complexes. Part 22. The Ionisation of 2,4-Dinitroaniline, its N-Alkylated Derivatives, and 2,6-Dinitroaniline in Methanol-Dimethyl Sulphoxide containing Sodium Methoxide
Crampton, Michael R.,Wilson, Penelope M.
, p. 1854 - 1858 (2007/10/02)
2,4-Dinitroaniline and its N-alkylated derivatives react with sodium methoxide in methanol-dimethyl sulphoxide to give conjugate base.However, in the case of 2,6-dinitroaniline, base addition at the 3-position competes with proton loss.The effects of N-alkylation on the acidity of 2,4-dinitroaniline are considered and are compared with the effects of similar substitution in 2,4,6-trinitroaniline.