13098-94-7Relevant articles and documents
Palladium-Catalyzed Direct Dicarbonylation of Amines with Ethylene to Imides
Kuai, Chang-Sheng,Wang, Le-Cheng,Xu, Jian-Xing,Wu, Xiao-Feng
supporting information, p. 451 - 456 (2022/01/04)
The selective and effective conversion of low-cost and simple bulk chemicals into high value-added products through catalytic strategy has a wide range of practical significance. Here, a palladium-catalyzed method for the direct and efficient dicarbonylation of amines with basic industrial feedstock ethylene to imide has been developed. Moderate to excellent yields of the desired imides can be produced from readily available amines in a straightforward manner.
Palladium-Catalyzed Esterification of Carboxylic Acids with Aryl Iodides
Kitano, Hiroyuki,Ito, Hideto,Itami, Kenichiro
supporting information, p. 2428 - 2432 (2018/04/27)
The first palladium-catalyzed esterification of carboxylic acids with aryl iodides is described. A palladium-based catalytic system consisting of IBnF (1,3-bis((pentafluorophenyl)methyl)imidazole-2-ylidene) ligand was found to significantly acc
An extremely efficient and green method for the acylation of secondary alcohols, phenols and naphthols with a deep eutectic solvent as the catalyst
Nguyen, Hai Truong,Tran, Phuong Hoang
, p. 98365 - 98368 (2016/10/31)
The typical deep eutectic solvent [CholineCl][ZnCl2]3, easily prepared from choline chloride and zinc chloride, is green and useful for the acylation of secondary alcohols, phenols, and naphthols with acid anhydrides. Its efficiency allows the acylation of sterically hindered secondary alcohols and acid anhydrides to proceed in high yield under mild condition. The catalyst is cheap, easy to handle, conveniently synthesized in a single step, and recyclable for several times without significant loss of catalytic activity.