1310105-60-2Relevant articles and documents
Enantioselective synthesis of diverse sulfinamides and sulfinylferrocenes from phenylglycine-derived chiral sulfinyl transfer agent
Han, Zhengxu S.,Meyer, Angelica M.,Xu, Yibo,Zhang, Yongda,Busch, Robert,Shen, Sherry,Grinberg, Nelu,Lu, Bruce Z.,Krishnamurthy, Dhileep,Senanayake, Chris H.
, p. 5480 - 5484 (2011/08/09)
A new chiral sulfinyl transfer auxiliary derived from readily available phenylglycine was developed. This auxiliary is utilized to synthesize a diverse array of alkyl- and arylsulfinamides and sulfinylferrocenes in high yields and excellent ee's. The desired products are produced in a one-pot sequence from the oxathiazolidine 2-oxide by two sequential nucleophilic additions that proceed in a stereospecific manner.