131140-40-4

Basic information

• Product Name: 2-{2-[(1R,2S,3R)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-allyl}-benzo[de]isoquinoline-1,3-dione
• Synonyms: 2-{2-[(1R,2S,3R)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-allyl}-benzo[de]isoquinoline-1,3-dione
• CAS NO: 131140-40-4
• Molecular Weight: 435.566
• Mol File: 131140-40-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-{2-[(1R,2S,3R)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-allyl}-benzo[de]isoquinoline-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{2-[(1R,2S,3R)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-allyl}-benzo[de]isoquinoline-1,3-dione(131140-40-4)
• EPA Substance Registry System: 2-{2-[(1R,2S,3R)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-allyl}-benzo[de]isoquinoline-1,3-dione(131140-40-4)

Safety Data

• Hazardous Substances Data: 131140-40-4(Hazardous Substances Data)

Upstream product

• 131140-36-8 (7E) 2-Methyl-6-(phenylmethyl)-7,9-decatrionate 
• 131140-33-5 (5E) 4-(Phenylmethyl)-5,7-octadien-1-ol 
• 131140-38-0 2-[(1S,2R,3S)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-acrylic acid ethyl ester 
• 131140-32-4 (5E) 1-(tert-Butyldimethylsilyloxy)-4-(phenylmethyl)-5,7-octadiene 
• 131140-30-2 1-(tert-Butyldimethylsilyloxy)-4-(phenylmethyl)pentanal 
• 131140-35-7 (E)-4-Benzyl-octa-5,7-dienal 
• 131140-28-8 3-benzyltetrahydro-2H-pyran-2-ol 
• 100-39-0 benzyl bromide 
• 32821-74-2 (±)-3-benzyltetrahydro-2H-pyran-2-one 
• 542-28-9 3,4,5,6-tetrahydro-2H-pyran-2-one 
• 81-83-4 1,8-Naphthalimide 
• 131140-39-1 2-[(1S,2R,3S)-3-Benzyl-2-((Z)-propenyl)-cyclopentyl]-prop-2-en-1-ol 

Relevant articles and documents

Catalytic iron-mediated ene carbocyclizations: Formal [4+4]-ene reactions of triene esters

2-Substituted-2,7,9-decatrienoates undergo an iron-catalyzed carbocyclization to yield trans-disubstituted cyclopentanes in moderate-to-good chemical yields. The cyclization products are formally the result of a [4+4]-ene reaction in which cis-propenyl and 2-acroyl functionalities are introduced as appendages to the newly formed cyclopentane ring by the cyclization. Triene ester substrates bearing an alkyl substituent at the 4- or 6-positions cyclize with high 1,2-stereoinduction to yield trisubstituted cyclopentanes in which the relative stereochemistry between three contiguous stereocenters is controlled.