13138-36-8

Basic information

• Product Name: (1-AMINOBUTYL)PHOSPHONIC ACID
• Synonyms: (1-AMINOBUTYL)PHOSPHONIC ACID;(1-AMINOBUTYL)PHOSPHONIC ACID 97%;(1-Aminobutyl)phosphonic acid,97%;alpha-Aminobutanephosphonic acid;alpha-Aminobutylphosphonic acid;DL-(1-Aminobutyl)phosphonic acid;NSC 117799;Phosphonic acid,P-(1-aMinobutyl)-
• CAS NO: 13138-36-8
• Molecular Formula: C4H12NO3P
• Molecular Weight: 153.12
• EINECS: 238-087-4
• Mol File: 13138-36-8.mol
• Article Data: 12

Chemical Properties

• Melting Point: 276-281 °C
• Boiling Point: 312.5 °C at 760 mmHg
• Flash Point: 142.8 °C
• Appearance: /solid
• Density: 1.300
• Vapor Pressure: 0.000115mmHg at 25°C
• PKA: 0.92±0.10(Predicted)
• CAS DataBase Reference: (1-AMINOBUTYL)PHOSPHONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: (1-AMINOBUTYL)PHOSPHONIC ACID(13138-36-8)
• EPA Substance Registry System: (1-AMINOBUTYL)PHOSPHONIC ACID(13138-36-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26-36
• Hazardous Substances Data: 13138-36-8(Hazardous Substances Data)

Usage

Chemical Properties

white crystalline powder

InChI:InChI=1/C4H12NO3P/c1-2-3-4(5)9(6,7)8/h4H,2-3,5H2,1H3,(H2,6,7,8)/p-1/t4-/m1/s1

Upstream product

• 109-74-0 propyl cyanide 
• 35051-49-1 2-diethoxyphosphoryl-pentanoic acid ethyl ester 
• 53327-51-8 (1-carbamoyl-butyl)-phosphonic acid diethyl ester 
• 60347-03-7 (1-butylidenehydrazino-butyl)-phosphonic acid diethyl ester 
• 25881-33-8 (1-benzylamino-butyl)-phosphonic acid 
• 67398-25-8 diphenyl 1-[(3-phenyl)thioureido]-n-butyl-phosphonate 
• 123-72-8 butyraldehyde 
• 20459-48-7 (1-amino-butyl)-phosphonic acid diethyl ester; hydrochloride 
• 7070-34-0 1,1-bis-acetylamino-butane 
• 83724-37-2 [1-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-butyl]-phosphonic acid diethyl ester 
• 79014-51-0 1-Isocyanbutylphosphonsaeure-diethylester 
• 114264-10-7 benzyl 1-(diethoxyphosphoryl)butylcarbamate 
• 83245-93-6 diethyl (1-amino-butyl)-phosphonate 

Relevant articles and documents

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POLYMERIZABLE PHOSPHONIC ACID DERIVATIVE AND ADHESIVE COMPOSITION COMPRISING THE SAME

The present invention provides an adhesive composition comprising a polymerizable phosphonic acid derivative which is a composition having intramolecularly a polymerizable group and a phosphonic acid group, represented by the general formula [1]: wherein R represents a polymerizable group;A represents an oxygen atom or a sulfur atom;Xqs represent independently an oxygen atom or a sulfur atom;Yqs represent independently the same or different organic group;Zqs may be independently the same or different from each other and, a part of the Zqs optionally selected or all of the Zqs represent organic groups having a substituent which is an organic group other than a polymerizable group and a phosphonic acid group;p is an integer from 1 to 10;q is an integer from 1 to p; when p is 1, q is 1;X1 represents an oxygen atom or a sulfur atom;Y1 represents an organic group;Z1 represents an organic group having one or more of substituents which are organic groups other than an acidic group and a polymerizable group, or a salt thereof. The adhesive composition or the salt thereof according to the present invention improve a shelf life and adhesion properties of an adhesive composition comprising essentially a (meth)acrylate monomer having intramolecularly an acidic group and water in dental treatment.

Synthesis of 1-Aminoalkylphosphonic Acids via Amidoalkylation of Phosphorous Acid by N,N'-Alkylidenbisamides

N,N'-Alkylidenebisamides 1, totally unsuitable as amidoalkylating agents toward phosphorous acid, react with its "activated" form prepared "in situ" from phosphorous(III) chloride and acetic acid to give the desired 1-amidoalkylphosphonic acids 2 in high yield.