1314-11-0Relevant articles and documents
The superconductor (Tl,Hg,Ca)2- (Ba,Sr)2(Ca,Sr,Tl)Cu2O7.6
Valldor, Martin,Bryntse, Ingrid,Morawski, Andrzej
, p. i126-i128 (2002)
The crystal structure of superconductor (Tl,Hg,Ca)2-(Ba,Sr)2(Ca,Sr,Tl)Cu2O7.6 was investigated. The compound contained both Tl and Hg in the charge reservoir (CR), Sr is located at both alkali-earth (AE) metal
Characterization of an alkaline earth metal-doped solid superacid and its activity for the esterification of oleic acid with methanol
Huang, Chien-Chang,Yang, Chieh-Ju,Gao, Pei-Jyuan,Wang, Nai-Ci,Chen, Ching-Lung,Chang, Jo-Shu
, p. 3609 - 3620 (2015/06/25)
The leaching of grafted sulfate groups is one of the major issues for the solid acid catalysts with sulfate modification. A detailed study of sulfated alkaline earth metal-ferric composite oxides was carried out to suppress the leaching of sulfate groups as well as maintain high reactivity during the esterification of oleic acid. The acid properties and quantities of the active sites present on the catalysts were studied with pyridine-adsorption, FT-IR, TGA, and titration methods. The following order of acidic strength was observed: SO42-/Sr-Fe oxide > SO42-/Ca-Fe oxide > SO42-/Mg-Fe oxide. After sulfate modification, sulfate ions are linked to the composite oxides in a bridged bidentate form. SO42-/Sr-Fe oxide exhibits superacidic nature due to the high induction effect of the sulfated ion grafted on the Sr cation. TGA and FT-IR spectroscopic analyses provide new insights into the function of the iron cations implanted on the catalyst surface for enhancing the turnover frequency (TOF) of the active sites on SO42-/Sr-Fe oxide in the esterification. It was verified that the active energy of SO42-/Sr-Fe oxide for the esterification of oleic acid with methanol was as low as 28.53 ± 0.72 kJ mol-1. In the reusability study, SO42-/Sr-Fe oxide exhibited high reusability in the esterification, due to the high stability of the sulfate ion grafted on SO42-/Sr-Fe oxide.
Synthesis and crystal structure of oxygen-deficient Bilayer Ruthenate Sr3Ru2O7-δ
Martinez-Anaya, Oliver,Garcia-Valdes, Jesus,De La Mora, Pablo,Tavizon, Gustavo
, p. 777 - 783 (2014/06/09)
The structural properties of oxygen-deficient Ruddlesden-Popper-type Sr3Ru2O7-δ compounds are presented. Sr3Ru2O7-δ compounds (δ≤0.17, 0.23, 0.28, 0.40, and 0.47) were obtained by hydrogen reduction of the parent Sr3Ru2O7 ruthenate. Rietveld structure refinements were performed to determine the crystal structure of the reduced compounds. Oxygen deficiency in the samples was studied by redox titrations and the Ru3+ content was confirmed by electron paramagnetic resonance. Magnetisation measurements were performed to study the magnetic response of the reduced phases. Removal of the oxygen atoms from the parent compound resulted in the decrease of the c-lattice parameter and increase of the a-lattice parameter that is related to partial reduction of Ru4+, in Sr3Ru2O7, to Ru3+. Rietveld analyses showed that the apical oxygen atoms of the RuO6 octahedra were partially lost during reduction. Redox titration experiments showed a linear correlation between reduction of the compounds and the annealing time under H2. CSIRO 2014.