131703-87-2

Basic information

• Product Name: (7S,5R)-methyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5,6,7,8-octahydro-5-<(2R)-2-ethyl-2,3-epoxypropyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate
• CAS NO: 131703-87-2
• Molecular Weight: 915.139
• Mol File: 131703-87-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (7S,5R)-methyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5,6,7,8-octahydro-5-<(2R)-2-ethyl-2,3-epoxypropyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (7S,5R)-methyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5,6,7,8-octahydro-5-<(2R)-2-ethyl-2,3-epoxypropyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate(131703-87-2)
• EPA Substance Registry System: (7S,5R)-methyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5,6,7,8-octahydro-5-<(2R)-2-ethyl-2,3-epoxypropyl>-7-(15-vindolinyl)azonino<5,4-b>indole-7-carboxylate(131703-87-2)

Safety Data

• Hazardous Substances Data: 131703-87-2(Hazardous Substances Data)

Upstream product

• 131703-84-9 (3aR,4R)-methyl 3-<(S)-α-methylbenzyl>-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131703-85-0 (3aR,4R)-methyl 3-<(S)-α-methylbenzyl>-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2-hydroxy-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 131703-83-8 methyl 3-<(S)-α-methylbenzyl>-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate acetonide 
• 131727-04-3 dimethyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5,6-hexahydroazepino<4,5-b>indole-5,5-dicarboxylate 
• 131703-74-7 methyl 3-<(S)-α-methylbenzyl>-1,2,3,4,5ξ,6-hexahydroazepino<4,5-b>indole-5-carboxylate 
• 131703-86-1 (3aR,4R)-methyl 3-<(S)-α-methylbenzyl>-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 2182-14-1 vindoline 

Relevant articles and documents

Enantioselective Syntheses of Vinblastine, Leurosidine, Vincovaline, and 20'-epi-Vincovaline

The binary indole-indoline alkaloids vinblastine (1), leurosidine (13), 20'-epi-vincovaline (14a), and vincovaline (14b) were obtained by coupling of vindoline (3) to the tetracyclic intermediates 7a, 7b or 22a, 22b, followed by reduction and cyclization