131829-79-3

Basic information

• Product Name: (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate
• CAS NO: 131829-79-3
• Molecular Weight: 462.589
• Mol File: 131829-79-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(131829-79-3)
• EPA Substance Registry System: (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2,3-dihydroxypropyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate(131829-79-3)

Safety Data

• Hazardous Substances Data: 131829-79-3(Hazardous Substances Data)

Upstream product

• 131703-67-8 (4R)-4-ethyl-4,5-dihydroxypentanal acetonide 
• 66859-30-1 methyl 3-benzyl-1,2,3,4,5,6-hexahydroazepino[4,5-b]indole-5-carboxylate 

Downstream Products

• 131703-72-5 C₆₃H₇₈N₄O₁₂SSi 
• 121485-40-3 C₆₃H₈₀N₄O₁₂SSi 
• 131829-86-2 (7S,5R)-methyl 3-benzyl-1,2,3,4,5,6,7,8-octahydro-5-((2R)-2-ethyl-2,3-epoxypropyl)-7-(15-vindolinyl)azonino[5,4-b]indole-7-carboxylate 
• 131703-71-4 (3aR,4S,11bS)-3-Benzyl-6-chloro-4-[(R)-2-(toluene-4-sulfonyloxymethyl)-2-trimethylsilanyloxy-butyl]-2,3,3a,4,5,6-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 
• 131829-73-7 (3aR,4R)-methyl 3-benzyl-2,3,3a,4,5,7-hexahydro-4-<(2R)-2-ethyl-2-<(trimethylsilyl)oxy>-3-<(p-tolylsulfonyl)oxy>propyl>-1H-pyrrolo<2,3-d>carbazole-6-carboxylate 
• 121464-77-5 (3aR,4R,11bS)-3-Benzyl-4-[(R)-2-hydroxy-2-(toluene-4-sulfonyloxymethyl)-butyl]-2,3,3a,4,5,7-hexahydro-1H-pyrrolo[2,3-d]carbazole-6-carboxylic acid methyl ester 

Relevant articles and documents

Enantioselective Syntheses of Vinblastine, Leurosidine, Vincovaline, and 20'-epi-Vincovaline

The binary indole-indoline alkaloids vinblastine (1), leurosidine (13), 20'-epi-vincovaline (14a), and vincovaline (14b) were obtained by coupling of vindoline (3) to the tetracyclic intermediates 7a, 7b or 22a, 22b, followed by reduction and cyclization