131968-96-2Relevant articles and documents
Synthesis of Synthetic Lubricants by Trimerization of 1-Decene and 1-Dodecene with Homogeneous Chromium Catalysts
Wasserscheid, Peter,Grimm, Siegfried,Koehn, Randolf D.,Haufe, Matthias
, p. 814 - 818 (2001)
The Cr-catalyzed trimerization of 1-decene and 1-dodecene is a highly selective method to synthesize C30 and C36 olefins. After hydrogenation, these products display very attractive viscosity indices (VI's). Due to the high trimer se
Metal Acetylide Elimination: The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines
Flynn, Matthew T.,Blair, Victoria L.,Andrews, Philip C.
supporting information, p. 1225 - 1228 (2018/04/30)
Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.
Synthesis of optically active 1-(1-phenylethyl)-1H-imidazoles derived from 1-phenylethylamine
Mloston, Grzegorz,Mucha, Paulina,Urbaniak, Katarzyna,Broda, Karolina,Heimgartner, Heinz
body text, p. 232 - 238 (2009/02/07)
The three-component reaction of (R)- or (S)-1-phenylethylamine (6), formaldehyde, and an α-(hydroxyimino) ketone 5, i.e., 3-(hydroxyimino) butan-2-one (5a) or 2-(hydroxyimino)-1,2-diphenylethanone (5b), yields the corresponding enantiomerically pure 1-(1-