132068-17-8

Basic information

• Product Name: N-(trimethylsilylmethyl)-1,2-disila-1,1,2,2-tetramesityltriazene
• CAS NO: 132068-17-8
• Molecular Weight: 662.153
• Mol File: 132068-17-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(trimethylsilylmethyl)-1,2-disila-1,1,2,2-tetramesityltriazene(CAS DataBase Reference)
• NIST Chemistry Reference: N-(trimethylsilylmethyl)-1,2-disila-1,1,2,2-tetramesityltriazene(132068-17-8)
• EPA Substance Registry System: N-(trimethylsilylmethyl)-1,2-disila-1,1,2,2-tetramesityltriazene(132068-17-8)

Safety Data

• Hazardous Substances Data: 132068-17-8(Hazardous Substances Data)

Upstream product

• 79184-72-8 2,2-dimesitylhexamethyltrisilane 
• 80785-72-4 tetramesityldisilene 
• 87576-94-1 trimethylsilylmethyl azide 

Relevant articles and documents

Reactions of tetramesityldisilene with azides: synthesis of disilaaziridines

The reactions of several organic azides (RN3) with tetramesityldisilene (1) were studied.Azides with R = Ph or Mes each gave two products, a disilaaziridine and a disilatriazoline.When R = PhCH2 or Me3SiCH2 intermediate adducts of the azide and the disilene were found.These adducts and the disilatriazolines both react thermally to yield the respective disilaaziridines.For R = Me3Si only a disilaaziridine was observed, the structure of which was determined by X-ray crystallography and was found to have a short Si-Si internuclear distance of 2.23 Angstroem.Crystal data: R = trimethylsilyl, a 23.561(3), b 19.001(3), c 16.916(3) Angstroem, monoclinic, β = 106.095 deg, C2/c, Z = 8.Novel five-membered silicon heterocycles were isolated from the reactions of 1 with toluenesulfonyl azide and diphenylphosphonyl azide.