132374-44-8Relevant articles and documents
Asymmetric Diels-Alder Reaction of Optically Active α-(2-exo-Hydroxy-10-bornyl)sulfinylmaleimides and its Application to Optically Active 5-Functionalised Pyrrolines via Retro-Diels-Alder Reaction
Arai, Yoshitsugu,Matsui, Makoto,Fujii, Akihito,Kontani, Tohru,Ohno, Toshiyuki,et al.
, p. 25 - 40 (2007/10/02)
Optically pure sulfinylmaleimides 1 have been synthesized.The Diels-Alder reactions of the sulfoxides 1 with various dienes showed high diastereoselectivity.Regioselective reduction of the adducts 4c and 6c followed by desulfination afforded the γ-hydroxy